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Highly Dispersed DPPF Locked in Knitting Hyper‐Crosslinked Polymers as Efficient and Recyclable Catalyst
Author(s) -
Tang Cheng,
Zou Zhijuan,
Fu Yufang,
Song Kunpeng
Publication year - 2018
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201800610
Subject(s) - catalysis , x ray photoelectron spectroscopy , scanning electron microscope , ferrocene , polymer , materials science , transmission electron microscopy , dispersion (optics) , chemical engineering , aqueous solution , nuclear chemistry , chemistry , nanotechnology , organic chemistry , composite material , electrode , electrochemistry , physics , optics , engineering
In this study, a novel catalytic system based on the hyper‐cross‐linked 1,1′‐Bis (diphenylphosphino) ferrocene (HCP‐DPPF) is prepared for effectively removing Cr (VI) from water. Transmission Electron Microscope (TEM), Scanning Electron Microscope (SEM) and X‐ray Photoelectron Spectroscopy (XPS) were employed for the characterization of the catalyst. The surface area of HCP‐DPPF can reach 349.7 m 2 g −1 and the SEM mapping shows that Fe has a good dispersion on the surface of polymer materials. The resulting HCP‐DPPF exhibited remarkable catalytic activity and excellent durability for the Cr (VI) removal and reduction of 4‐nitrophenol (4‐NP) to 4‐aminophenol (4‐AP) in an aqueous solution. It could reach nearly 100% conversions within several minutes, even when the amount of the catalyst was used as low as 3 mg. Moreover, the HCP‐DPPF can be reused 14 times and still retain high conversion efficiency over 92%. The results illustrate in situ immobilization of DPPF onto hyper‐cross‐linked polymers which improve the stability and electron transfer of the catalyst, while enhancing the activity of HCP‐DPPF toward Cr (VI) removal and reduction of 4‐NP.