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Phenyltetrazole as a New Ligand for Immobilization of Palladium Nanoparticles on SBA‐15: A New Robust Catalyst with High Loading of Pd for Rapid Oxidation and Reduction
Author(s) -
Moghaddam Firouz M.,
Saberi Vahid,
Kalvani Pedram
Publication year - 2018
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201800453
Subject(s) - palladium , catalysis , fourier transform infrared spectroscopy , scanning electron microscope , thermogravimetric analysis , materials science , nanoparticle , infrared spectroscopy , transmission electron microscopy , surface modification , spectroscopy , chemical engineering , scanning transmission electron microscopy , nuclear chemistry , chemistry , nanotechnology , organic chemistry , composite material , physics , quantum mechanics , engineering
Abstract In this work, a new catalyst based on palladium nanoparticle supported SBA‐15 has been introduced. The designed catalyst was characterized by Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier‐transform infrared spectroscopy (FT‐IR), Brunauer–Emmett–Teller (BET) surface area analysis, thermo gravimetric analysis (TGA), Energy‐dispersive X‐ray spectroscopy (EDS) and atomic absorption spectroscopy (AAS) analyses. For the first time, phenyltetrazole has been used as a ligand to the functionalization of SBA‐15 to design robust heterogeneous catalyst with high‐loading metal for reduction and oxidation in short time using a low amount of the catalyst.