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Facile Solvent‐ and Metal‐Free Synthesis of Polymers Including Triazole by Click Reaction
Author(s) -
RanjbarKarimi Reza,
Mehrafarin Ali,
Mahyari Amir,
Mehrabi Hossein
Publication year - 2018
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201800266
Subject(s) - click chemistry , differential scanning calorimetry , polymer , polymer chemistry , solvent , catalysis , materials science , infrared spectroscopy , gel permeation chromatography , triazole , chemistry , organic chemistry , physics , thermodynamics
A convenient green and rapid synthesis has been developed for the preparation of new polymers including 1,2,3‐triazole under solvent‐free conditions. These polymers were synthesized via a click reaction between alkynes and azido containing polymers in excellent yields without any catalyst for 3 minutes. The synthesized polymers were characterized by 1 H and 13 C nuclear magnetic resonance (NMR), gel permission chromatography (GPC), differential scanning calorimetry (DSC) and infrared (IR) spectroscopy.