Adsorption and Decomposition of DMMP on Size‐Selected (WO 3 ) 3  Clusters | Zendy

Tang Xin | Zendy; Hicks Zachary | Zendy; Ganteför Gerd | Zendy; Eichhorn Bryan W. | Zendy; Bowen Kit H. | Zendy

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Adsorption and Decomposition of DMMP on Size‐Selected (WO 3 ) 3 Clusters

Author(s) -

Tang Xin,

Hicks Zachary,

Ganteför Gerd,

Eichhorn Bryan W.,

Bowen Kit H.

Publication year - 2018

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201800229

Subject(s) - x ray photoelectron spectroscopy , dimethyl methylphosphonate , adsorption , decomposition , dimethyl ether , chemistry , methanol , inorganic chemistry , chemical engineering , organic chemistry , engineering

The adsorption and decomposition behaviors of dimethyl methylphosphate (DMMP) on size‐selected (WO 3 ) 3 clusters were studied by a combination of X‐ray Photoelectron Spectroscopy (XPS) and Temperature Programmed Reaction (TPR). The fate of DMMP adsorbed on (WO 3 ) 3 clusters was found to be very similar to its fate on (MoO 3 ) 3 . In contrast to DMMP on (MoO 3 ) 3 , however, dimethyl ether was observed as a product in the reaction of DMMP with (WO 3 ) 3 , in addition to methanol, due to the higher Lewis acidity of (WO 3 ) 3 clusters as compared to (MoO 3 ) 3 .

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