Syntheses of Nitronium Salts: A New Strategy towards Solid Nitronium Monosulfates | Zendy

Zelenov Victor P. | Zendy; Bukalov Sergey S. | Zendy; Leites Larissa A. | Zendy; Bushmarinov Ivan S. | Zendy; Struchkova Marina I. | Zendy; Dmitrienko Artem O. | Zendy; Tartakovsky Vladimir A. | Zendy

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Syntheses of Nitronium Salts: A New Strategy towards Solid Nitronium Monosulfates

Author(s) -

Zelenov Victor P.,

Bukalov Sergey S.,

Leites Larissa A.,

Bushmarinov Ivan S.,

Struchkova Marina I.,

Dmitrienko Artem O.,

Tartakovsky Vladimir A.

Publication year - 2017

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201702791

Subject(s) - chemistry , medicinal chemistry

A new approach towards nitronium salts via the reaction of CF 3 COONO 2 (TFAN) with acids was developed. This method was applied to the syntheses of the following solid nitronium salts: NO 2 HSO 4 ( 1 ), NO 2 HS 2 O 7 ( 2 ), (NO 2 ) 2 S 2 O 7 ( 3 ), (NO 2 )(CF 3 CO)SO 4 ( 4 ), NO 2 ClO 4 ( 5 ), (NO 2 )CF 3 SO 3 ( 6 ), (NO 2 )FSO 3 ( 7 ), NO 2 IO 4 ( 8 ), (NO 2 )(CF 3 CO)S 2 O 7 ( 9 ), and NO 2 BF 4 ( 10 ) (71–95%). Nitronium monosulfates 1 and 4 as well as compounds 8 , 9 and NO 2 HS 3 O 10 ( 11 ) were obtained for the first time. The structures of compounds 3 and 4 were confirmed by powder X‐ray diffraction.

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