Catalytic Oxidation of Biosourced 3‐Methylphtalic Anhydride under O 2 : One‐Pot Hemimellitic Acid Synthesis and Novel Example of Biomass Valorization. | Zendy

Giorgi Pascal D. | Zendy; SooTang SiuHa | Zendy; Antoniotti Sylvain | Zendy; van der Waal Jan C. | Zendy

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Catalytic Oxidation of Biosourced 3‐Methylphtalic Anhydride under O 2 : One‐Pot Hemimellitic Acid Synthesis and Novel Example of Biomass Valorization.

Author(s) -

Giorgi Pascal D.,

SooTang SiuHa,

Antoniotti Sylvain,

van der Waal Jan C.

Publication year - 2017

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201702274

Subject(s) - catalysis , moiety , chemistry , organic chemistry , acid anhydride , biomass (ecology) , combinatorial chemistry , biology , epoxy , agronomy

An original one pot/two steps scalable catalytic reaction was developed for the synthesis of hemimellitic acid from biobased 3‐methylphtalic anhydride. This novel approach, involving an anhydride function as a masked 1,2‐dicarboxylic acid moiety, allowed circumventing undesired complexation issues of intermediates with catalytically active metal species and thereby requalify Co/Mn/Br catalytic system under O 2 in relatively mild conditions.

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