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Deep Axial Inclusion of Two Aromatic Molecules by Dimethyl‐β‐Cyclodextrin and β‐Cyclodextrin
Author(s) -
Kobayashi Yayoi,
Hoshi Tomonori,
Yamamoto Satoshi,
Kimura Mutsumi,
Kobayashi Nagao
Publication year - 2017
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201702089
Subject(s) - cyclodextrin , chemistry , hydroquinone , molecule , circular dichroism , inclusion compound , computational chemistry , crystallography , organic chemistry
Electronic absorption, induced circular dichroism, and 1 H NMR spectroscopies, together with molecular orbital calculations, have indicated the attainment of a deep axial inclusion of two aromatic molecules by β‐cyclodextrin and dimethyl‐β‐cyclodextrin, by selecting quinhydrone (1:1 compound consisting of benzoquinone and hydroquinone) as a guest molecule.