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Bis{ cis ‐[MoO 2 ]} Complexes of 4,6‐Diacetyl Resorcinol Bis(hydrazone)and Their Catalytic Application for the Three Components Dynamic Covalent Assembly via Hantzsch Reaction
Author(s) -
Maurya Mannar R.,
Rana Lata,
Jangra Nancy,
Avecilla Fernando
Publication year - 2017
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201701629
Subject(s) - chemistry , catalysis , medicinal chemistry , acetylacetone , hydrazone , schiff base , resorcinol , dibasic acid , thermogravimetric analysis , benzaldehyde , ethyl acetoacetate , octahedral molecular geometry , ligand (biochemistry) , polymer chemistry , crystal structure , inorganic chemistry , crystallography , organic chemistry , biochemistry , receptor
Abstract Four binuclear dioxidomolybdenum(VI) complexes with Schiff base ligands, H 4 dar(bhz) 2 ( I ), H 4 dar(inh) 2 ( II ), H 4 dar(nah) 2 ( III ) and H 4 dar(fah) 2 ( IV ) (H 2 dar=4,6‐diacetyl resorcinol and Hbhz=benzoylhydrazide, Hinh=isonicotinoylhydrazide, Hnah=nicotinoylhydrazide, and Hfah=2‐furoylhydrazide) have been prepared by the reaction of ligand with [Mo VI O 2 (acac) 2 ] (Hacac=acetylacetone) in 1:2 ratio in methanol. Isolated complexes[(Mo VI O 2 ) 2 {dar(bhz) 2 }(H 2 O) 2 ] ( 1 ), [(Mo VI O 2 ) 2 {dar(inh) 2 }(H 2 O) 2 ] ( 2 ), [(Mo VI O 2 ) 2 {dar(nah) 2 }(H 2 O) 2 ] ( 3 ) and [(Mo VI O 2 ) 2 {dar(fah) 2 }(H 2 O) 2 ] ( 4 ) are characterized by elemental (CHN) analysis, spectral (FT‐IR, UV‐vis, 1 H and 13 C NMR) and thermogravimetric analysis. Single crystal X‐ray diffraction analysis of complexes 1 , 2 and 4 confirms their binuclear structure and distorted octahedral geometry around each molybdenum where ligands behave as bis(dibasic tridentate) coordinating through phenolic oxygen, azomethine nitrogen and enolic oxygen atoms of each unit. These complexes have successfully been used as catalyst precursors in solvent as well as solvent free conditions for the one‐pot three components (ethylacetoacetate, benzaldehyde and ammonium acetate) dynamic covalent assembly, via Hantzsch reaction using hydrogen peroxide as an oxidant.

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