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Microwave‐Assisted Efficient Suzuki‐Miyaura Cross‐Coupling Reactions in Water Catalyzed by Nano‐Pd/gC 3 N 4 Composite
Author(s) -
Sharma Sonam,
Nazir Roshan,
Pande Surojit,
Sarkar Bibhas R.
Publication year - 2017
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201701527
Subject(s) - catalysis , halide , composite number , aryl , microwave , nano , microwave irradiation , solvent , heterogeneous catalysis , chemistry , palladium , coupling reaction , chemical engineering , materials science , photochemistry , organic chemistry , composite material , alkyl , physics , quantum mechanics , engineering
Microwave assisted Suzuki cross‐coupling of aryl halides with different arylboronic acids were obtained using nano‐Pd/gC 3 N 4 composite as catalyst in water as solvent under aerobic conditions. Catalyst was found to be highly efficient exhibiting high TOFs ∼ 12,000 h −1 for a spectrum of substituted reactants exemplifying unique green chemistry approach combining efficient reusable catalysis in water in presence of air and using microwave irradiation as alternative heating mode.