Bio‐inspired Catalyst: [( μ ‐(SCH(CH 2 CH 3 )CH 2 S))Fe(CO) 5 ] 2 (μ,k 1 ,k 1 ‐DPPF) for Proton Reduction and Phenol Hydroxylation | Zendy

Zhang Xia | Zendy; Zhang Tianyong | Zendy; Li Yiwen | Zendy; Li Bin | Zendy; Jiang Shuang | Zendy; Du Ping | Zendy; Zhang Guanghui | Zendy; Hai Li | Zendy; Ma Xiaoyuan | Zendy; Wu Wubin | Zendy; Liu Mengdi | Zendy

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Bio‐inspired Catalyst: [( μ ‐(SCH(CH 2 CH 3 )CH 2 S))Fe(CO) 5 ] 2 (μ,k 1 ,k 1 ‐DPPF) for Proton Reduction and Phenol Hydroxylation

Author(s) -

Zhang Xia,

Zhang Tianyong,

Li Yiwen,

Li Bin,

Jiang Shuang,

Du Ping,

Zhang Guanghui,

Hai Li,

Ma Xiaoyuan,

Wu Wubin,

Liu Mengdi

Publication year - 2017

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201701449

Subject(s) - reactivity (psychology) , chemistry , catalysis , hydroxylation , phenol , ferrocene , selectivity , medicinal chemistry , hydride , hydrogen , single crystal , crystallography , inorganic chemistry , organic chemistry , electrochemistry , enzyme , medicine , alternative medicine , electrode , pathology

A new [Fe−Fe]‐hydrogenase model complex [( μ ‐(SCH(CH 2 CH 3 )CH 2 S))Fe(CO) 5 ] 2 (μ,k 1 ,k 1 ‐DPPF) (DPPF=1,1′‐bis(diphenylphosphino)ferrocene) 2 was prepared and characterized by solution IR spectrum, NMR spectrum and single‐crystal X‐ray diffraction. The electrocatalytic property and phenol hydroxylation reactivity were investigated. In the absence of HOAc, complex 2 can catalyse proton reduction to hydrogen at −2.36 V. In addition, complex 2 also could catalyse the hydroxylation of phenol with the maximal phenol conversion (56.8%) and dihydroxybenzene selectivity (78.4%).

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