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Copper‐Exchanged Magnetic‐FAp: Surface Catalysis in Decarboxylative Coupling of α ‐Oxocarboxylic Acids with Formamides
Author(s) -
Mirfarjood SeyedAbdollah,
Mamaghani Manouchehr,
Sheykhan Mehdi
Publication year - 2017
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201701438
Subject(s) - formamides , copper , fluorapatite , catalysis , coupling (piping) , chemistry , oxide , decarboxylation , copper oxide , inorganic chemistry , chemical engineering , materials science , organic chemistry , metallurgy , mineralogy , apatite , engineering
An unprecedented heterogeneous catalysis in the decarboxylative coupling of α ‐oxocarboxylic acids is developed. A novel copper‐containing magnetic catalyst was synthesized by introducing copper into calcium fluorapatite encapsulated iron oxide. This catalyst led to the synthesis of α ‐ketoamides with a promising TON exceeding 1200.
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