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Kinetic Studies of Bischloroimide Monomers for the Facile Synthesis of Different Molecular Architecture Poly(phthalimide‐ co ‐naphthalimide)s
Author(s) -
Mushtaq Nafeesa,
Chen Guofei,
Sidra Lala Rukh,
Zhang Anjiang,
Fang Xingzhong
Publication year - 2017
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201700773
Subject(s) - phthalimide , copolymer , monomer , polymer chemistry , reactivity (psychology) , thermal stability , glass transition , condensation polymer , materials science , chemistry , organic chemistry , polymer , medicine , alternative medicine , pathology
A series of different molecular architecture (homo, random, block and gradient type) copolymers PI‐3(a–e) were synthesized by solution polycondensation. Three different bischloroimide monomers [bischlorophthalimide 2 a, bischloronaphthalimide 2 b and bischloro (naphthalimide‐phthalimide) 2 c ] were prepared and reacted with 4,4′‐thiobisbenzenethiol by different synthetic routes. The chemical reactivity of these monomers 2(a–c) was examined by kinetic study of model compounds N ‐phenyl‐4‐chloro‐1,8‐naphthalimide and N ‐phenyl‐4‐chlorophthalimide using gas chromatography mass spectrometry (GC‐MS). The difference in chemical reactivity of monomers was utilized to design molecular architecture of copolymer, and the influence of comonomers sequence on copolymer properties is investigated. The synthesized copolyimides PI‐3(a–e) integrated the excellent properties of naphthalimide and phthalimide as good organosolubility, high glass transition temperature of 198–319 °C and good thermooxidative stability based on 5 % weight loss temperature of 492–524 °C and 480–532 °C in nitrogen and air, respectively. Gradient type sequence PI‐3 e offers a good combination of phthalimide and naphthalimide groups in copolymers for improved thermal and mechanical properties.