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Palladium/Amine Complex Catalyzed Suzuki–Miyaura Reaction of Arylboron Compounds in Water
Author(s) -
Li Xinmin,
Liu Chun,
Wang Lei,
Ye Qing,
Jin Zilin
Publication year - 2017
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201700682
Subject(s) - palladium , amine gas treating , chemistry , aryl , catalysis , halide , aryl halide , potassium , organic chemistry , alkyl
An air‐stable palladium/amine complex Pd(OAc) 2 [( i ‐Pr) 2 NH] 2 was first synthesized and well characterized. This complex demonstrated high efficiency for the Suzuki‐Miyaura reactions of (hetero)aryl halides with arylboronic acids, potassium aryltrifluoroborotes and aryl N ‐methyliminodiacetic acid boronates in water without any additives.
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