ESP‐Promoted Suzuki‐Miyaura Cross‐Coupling and Peptide Bond Formation Reactions in Water at Room Temperature | Zendy

Konwar Manashjyoti | Zendy; Boruah Preeti Rekha | Zendy; Saikia Prakash J. | Zendy; Khupse Nageshewar D. | Zendy; Sarma Diganta | Zendy

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ESP‐Promoted Suzuki‐Miyaura Cross‐Coupling and Peptide Bond Formation Reactions in Water at Room Temperature

Author(s) -

Konwar Manashjyoti,

Boruah Preeti Rekha,

Saikia Prakash J.,

Khupse Nageshewar D.,

Sarma Diganta

Publication year - 2017

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201700638

Subject(s) - chemistry , aqueous medium , coupling reaction , catalysis , palladium , aqueous solution , ligand (biochemistry) , solvent , combinatorial chemistry , organic chemistry , receptor , biochemistry

A potential green protocol for C−C and C−N bond formation reactions in aqueous medium promoted by basic waste biomass has been developed. The protocol involves the use of Egg Shell Powder (ESP) in water as a green heterogeneous reaction media which is basic in nature and offers a mild, resourceful and inexpensive alternative to the conventional protocols for palladium catalyzed C−C (Suzuki‐Miyaura) and C−N (Peptide coupling) bond formation reactions. The reactions proceeded in basic ESP medium in air at short reaction time at room temperature under ‘external base/external promoter/ligand/organic solvent’ free conditions.

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