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Fabrication of Visible‐Light‐Responsive InVO 4 for Photoreduction of CO 2
Author(s) -
Singhal Nikita,
Kumar Umesh
Publication year - 2017
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201700527
Subject(s) - triethanolamine , visible spectrum , photocatalysis , scanning electron microscope , x ray photoelectron spectroscopy , materials science , transmission electron microscopy , catalysis , diffuse reflectance infrared fourier transform , photochemistry , hydrothermal circulation , vanadate , chemical engineering , nuclear chemistry , nanotechnology , chemistry , analytical chemistry (journal) , optoelectronics , organic chemistry , engineering , metallurgy , composite material
The gradual rise in anthropogenic CO 2 concentration in the atmosphere leads to global warming, and hence draws attention to develop different catalysts for CO 2 reduction to fuel. Indium vanadate has attractive photocatalytic properties under visible light. InVO 4 was synthesized by a hydrothermal method without using any organic precursor. Catalyst was well characterized with different techniques involving X‐ray diffraction, UV‐Vis diffuse reflectance spectroscopy, scanning electron microscopy, transmission electron microscopy, X‐ray photoelectron microscopy and thermal gravimetric analysis. Its catalytic performance was evaluated for photoreduction of CO 2 in a batch reactor under visible light irradiation. 520 ppm of CO was obtained in presence of triethanolamine (TEOA) as an electron donor.

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