Synthesis and Characterization of First Row Metal Complexes Derived from a Pyridinophane Ligand Functionalized by Fluoroalcohol | Zendy

Guillo Pascal | Zendy; Daran JeanClaude | Zendy; Manoury Eric | Zendy; Poli Rinaldo | Zendy

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Synthesis and Characterization of First Row Metal Complexes Derived from a Pyridinophane Ligand Functionalized by Fluoroalcohol

Author(s) -

Guillo Pascal,

Daran JeanClaude,

Manoury Eric,

Poli Rinaldo

Publication year - 2017

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201700404

Subject(s) - octahedron , chemistry , metal , ligand (biochemistry) , crystallography , characterization (materials science) , octahedral molecular geometry , stereochemistry , materials science , crystal structure , receptor , organic chemistry , nanotechnology , biochemistry

A new tetradentate N‐donor ligand ( L ) based on 2,11‐diaza[3.3](2,6)pyridinophane with N‐bonded (CF 3 ) 2 (OH)CCH 2 groups is presented, along with the coordination compounds [( L )FeCl 2 ][FeCl 4 ], [( L )MnCl 2 ], [( L )Cu(OAc) 2 ] and [( L )Zn(OTf)(H 2 O)](OTf) (OAc=acetate; OTf=trifluomethylsulfonate). All metal complexes possess a distorted octahedral geometry around the metal center.

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