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Understanding ZIF‐8 Performance upon Gas Adsorption by Means of Inelastic Neutron Scattering
Author(s) -
Casco Mirian E.,
FernándezCatalá Javier,
Cheng Yongqiang,
Daemen Luke,
RamirezCuesta Anibal J.,
CuadradoCollados Carlos,
SilvestreAlbero Joaquin,
RamosFernandez Enrique V.
Publication year - 2017
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201700250
Subject(s) - adsorption , inelastic neutron scattering , neutron scattering , zeolitic imidazolate framework , molecule , neutron , materials science , chemical engineering , chemical physics , chemistry , metal organic framework , nuclear physics , physics , organic chemistry , engineering
Despite the vast number of publication dealing with ZIF‐8, the performance of this zeolitic MOF upon adsorption is still a matter of debate. The understanding of its adsorption properties its of great importance to define its potential in aplications such as gas separation, sensing and catalytic processes. Using inelastic neutron scattering (INS) upon exposure to different probe molecules we get further insight about the adsortion performance at cryogenic temperatures, including the possible swinging of the imidazolate linkers.