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A Comparative Study of Electrochemical, Spectroscopic and Structural Properties of Phenyl, Thienyl and Furyl Substituted Ethylenes
Author(s) -
Viglianti Lucia,
VillafioritaMonteleone Francesca,
Botta Chiara,
Mussini Patrizia R.,
Ortoleva Emanuele,
Cauteruccio Silvia,
Licandro Emanuela,
Baldoli Clara
Publication year - 2017
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201700109
Subject(s) - electrochemistry , solid state , chemistry , computational chemistry , aggregation induced emission , molecule , stereochemistry , organic chemistry , physics , fluorescence , electrode , quantum mechanics
a detailed electrochemical and photophysical comparative study of three parallel series of phenyl, thienyl and furyl substituted ethylenes has been carried out, implemented by the computational calculation of selected terms. Relationships have been highlighted between molecular structure (number and type of aromatic rings) and important functional properties (in particular, electronic features and oligomerization ability). Interestingly, some of the studied heteroaryl‐ethylenes show emission in the solid state displaying an aggregation‐induced emission behavior.