Premium
Melamine and Spermine Mediated Supramolecular self–assembly of Octaphosphonate Tetraphenyl Porphyrin
Author(s) -
Bhosale Rajesh S.,
La Duong Duc,
Al Kobaisi Mohammad,
Bhosale Sidhanath V.,
Bhosale Sheshanath V.
Publication year - 2017
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201601864
Subject(s) - melamine , spermine , supramolecular chemistry , porphyrin , self assembly , methylene , fluorescence , polymer chemistry , chemistry , nanostructure , copolymer , supramolecular polymers , materials science , photochemistry , crystallography , organic chemistry , polymer , nanotechnology , crystal structure , enzyme , physics , quantum mechanics
We demonstrate the supramolecular self‐assembly of {porphyrin‐5,10,15,20‐tetrayltetrakis[(benzene‐5,1,3‐triyl)bis (methylene)]}octakis(phosphonic acid) 1 in the presence of melamine and spermine. The morphology of 1 in the presence of melamine and spermine was different, indicated that change in analytes could be used to control nanostructures. UV‐vis and fluorescence spectroscopic methods were employed to investigate aggregation mode. The self‐assembled nanostructure was confirmed by SEM imaging and XRD measurements.