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Acid‐Functionalized Mesoporous SBA‐15 as an Efficient Heterogeneous Organocatalyst for the Green Synthesis of β‐Amino Alcohol Derivatives
Author(s) -
Ghosh Swarbhanu,
Bhanja Piyali,
Molla Rostam Ali,
Khatun Resmin,
Islam Sk. Manirul
Publication year - 2017
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201601782
Subject(s) - chemistry , nucleophile , catalysis , epoxide , mesoporous material , mesoporous organosilica , alcohol , organic chemistry , reactivity (psychology) , nucleophilic addition , combinatorial chemistry , mesoporous silica , medicine , alternative medicine , pathology
SBA‐15 has been post‐synthesized for modification to sketch highly arranged AFS‐1, ‐COOH functionalized mesoporous hybrid organosilica. This hybrid organosilica has been utilized as a good mesoporous organocatalyst to synthesize 2‐amino alcohols under the application of mild conditions without co‐catalyst of any other metal. The material has reactivity for nucleophilic reaction of nucleopholic aromatic amines with epoxide under the application of solvent free condition and for the synthesis of 2‐amino alcohols from different kind of epoxides at normal temperature. To produce 2‐amino alcohols it has shown outstanding elevated catalytic efficiency in neat condition.