A Flexible Porous MOF Exhibiting Reversible Breathing Behavior through Single‐Crystal to Single‐Crystal Transformation | Zendy

Wang Lin | Zendy; He WeiWei | Zendy; Yao ZhaoQuan | Zendy; Hu TongLiang | Zendy

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A Flexible Porous MOF Exhibiting Reversible Breathing Behavior through Single‐Crystal to Single‐Crystal Transformation

Author(s) -

Wang Lin,

He WeiWei,

Yao ZhaoQuan,

Hu TongLiang

Publication year - 2017

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201601666

Subject(s) - porosity , materials science , luminescence , ligand (biochemistry) , crystal (programming language) , single crystal , breathing , transformation (genetics) , layer (electronics) , chemical engineering , atmosphere (unit) , crystallography , photochemistry , chemistry , nanotechnology , optoelectronics , composite material , receptor , computer science , thermodynamics , medicine , biochemistry , gene , engineering , physics , anatomy , programming language

A two dimensional (2D) flexible Zn(II) MOF (1) with intra‐layer channels has been synthesized using a mixed ligand strategy. Interestingly, 1 exhibits reversible breathing behavior upon desolvation/resolvation in crystal state, causing responsive luminescence together with visible color changes. Furthermore, the above‐mentioned process even occurred when 1 exposed to humid atmosphere or immersed in various organic solvents.

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