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A Flexible Porous MOF Exhibiting Reversible Breathing Behavior through Single‐Crystal to Single‐Crystal Transformation
Author(s) -
Wang Lin,
He WeiWei,
Yao ZhaoQuan,
Hu TongLiang
Publication year - 2017
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201601666
Subject(s) - porosity , materials science , luminescence , ligand (biochemistry) , crystal (programming language) , single crystal , breathing , transformation (genetics) , layer (electronics) , chemical engineering , atmosphere (unit) , crystallography , photochemistry , chemistry , nanotechnology , optoelectronics , composite material , receptor , computer science , thermodynamics , medicine , biochemistry , gene , engineering , physics , anatomy , programming language
A two dimensional (2D) flexible Zn(II) MOF (1) with intra‐layer channels has been synthesized using a mixed ligand strategy. Interestingly, 1 exhibits reversible breathing behavior upon desolvation/resolvation in crystal state, causing responsive luminescence together with visible color changes. Furthermore, the above‐mentioned process even occurred when 1 exposed to humid atmosphere or immersed in various organic solvents.