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A New Strategy towards Efficient and Recyclable Carbon‐Chloride Bond Cleavage of Environmentally Harmful Organochlorides through Electrochemical Catalysis in Non–aqueous Media
Author(s) -
Zhu Weihua,
Huang Tingting,
Li Minzhi,
Zheng Limin,
Bao Songsong,
Kobayashi Nagao,
Liang Xu
Publication year - 2017
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201601603
Subject(s) - catalysis , electrochemistry , chemistry , bond cleavage , porphyrin , aqueous solution , aqueous medium , transition metal , chloride , cleavage (geology) , carbon fibers , environmentally friendly , electrocatalyst , combinatorial chemistry , organic chemistry , materials science , electrode , ecology , fracture (geology) , composite number , composite material , biology
Transition metal coordinated porphyins generally exhibit effective carbon‐chloride bond cleavage of environmentally harmful organochlorides through electrochemical reductive catalysis in non‐aquaous media, but the recyclable use of the catalyst remains a challenge. In this manuscirpt, a new strategy of an efficient and recyclable C−Cl bond cleavage is described, and the structural characterization, electrochemical behaviour and electrochemical catalysis were illustrated by various techniques. It is demonstrated that the Fe 3 O 4 @SiO 2 @Co(II)porphyrin magnetic materials can be effectively used for at least 30 cycles.