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Bulky bis(imidazole) and 2‐sulfoterephthalate Assisted 3‐D Cu(II) and 2‐D Mn(II) Coordination Polymers: Topology, Diversity in Metal Containing Nodes and Spectral Elucidation
Author(s) -
Das Kuheli,
Datta Amitabha,
Mane Sandeep B.,
Mendiratta Shruti,
Massera Chiara,
Garribba Eugenio,
Huang JuiHsien,
Hung ChenHsiung,
Akitsu Takashiro
Publication year - 2016
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201601260
Subject(s) - carboxylate , electron paramagnetic resonance , imidazole , crystallography , bifunctional , chemistry , sulfonate , solvent , topology (electrical circuits) , metal , metal ions in aqueous solution , stereochemistry , magnetic susceptibility , polymer chemistry , physics , combinatorics , organic chemistry , mathematics , nuclear magnetic resonance , sodium , catalysis
This work presents the synthesis of a 3‐D Cu(II) framework represented by a 4,6‐c 2‐nodal net of the type fsc employing the bifunctional template group sulfonate‐carboxylate and the dia precursor (dia=9,10‐di(1H‐imidazol‐1‐yl)anthracene). The high versatility of the N‐donor and carboxylate ligands also yields a 2‐D Mn chain described by a pcu primitive cubic net. The solvent‐dependent EPR studies for both the CPs are also illustrated. Variable temperature magnetic susceptibility confirms that both ferromagnetic and antiferromanetic interactions coexist in 1 among the different geometrical arrangement of Cu(II) ions.