Unexpected Diversity within Solid‐State Structures of Methanetrisulfonate Salts | Zendy

Oelkers Benjamin | Zendy; Schaffner Dirk | Zendy; Sun Yu | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Unexpected Diversity within Solid‐State Structures of Methanetrisulfonate Salts

Author(s) -

Oelkers Benjamin,

Schaffner Dirk,

Sun Yu

Publication year - 2016

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201601200

Subject(s) - alkali metal , ammonium , salt (chemistry) , aqueous solution , solid state , chemistry , inorganic chemistry , crystallography , transition metal , coordination number , ion , organic chemistry , catalysis

The structural properties of various salts of methanetrisulfonic acid (H 3 mts) are described, spanning the free acid, ammonium and alkali metals (Na, K, Cs), first row transition metals (Cr, Co−Zn), and lead. A number of different coordination modes is found, including unexpected motifs such as the κ 3 O 1,4,7 coordination in the lead salt and anions of the type [M(H 2 O) 4 (κ 2 O 1,4 ‐mts)] − (M=Co, Ni, Zn), which do not seem to be persistent in aqueous solution.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research