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A Performant Dry Reforming Catalytic System Elaborated from the Reductive Decomposition of BaNi 2 V 2 O 8
Author(s) -
GuerreroCaballero Jesus,
Löfberg Axel,
Mentré Olivier,
Kane Tanushree,
Pussacq Tanguy,
Roussel Pascal,
Huvé Marielle,
Trentesaux Martine,
Gardoll Olivier,
Kabbour Houria
Publication year - 2016
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201601109
Subject(s) - catalysis , decomposition , methane , redox , oxide , carbon dioxide reforming , selectivity , deposition (geology) , materials science , chemistry , inorganic chemistry , chemical engineering , syngas , metallurgy , organic chemistry , engineering , paleontology , sediment , biology
The reductive decomposition of BaNi 2 V 2 O 8 leads to a Ni‐supported catalyst composed by an intimate blend of Ba 3 (VO 4 ) 2 /Ni/BaV 10 O 15 . High activity for the Dry Reforming of Methane (DRM) is attained with 85 % conversion for CH 4 and CO 2 , as well as a very good stability in time and a high selectivity with H 2 /CO=0.9 and negligible carbon deposition. A rich redox and optimal oxide‐metal interactions provide a unique and promising catalytic system.