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Hydrogen Optical Metamaterial Sensor Based on Pd Dendritic Nanostructures
Author(s) -
RochaRodrigues Pedro,
HierroRodriguez Aurelio,
Guerreiro Ariel,
Jorge Pedro,
Santos José Luís,
Araújo João Pedro,
Teixeira José Miguel
Publication year - 2016
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201600833
Subject(s) - materials science , hydrogen , nanoporous , fabrication , hydrogen sensor , absorption (acoustics) , nanostructure , desorption , metamaterial , transient (computer programming) , nanotechnology , optoelectronics , analytical chemistry (journal) , adsorption , chemistry , palladium , catalysis , composite material , chromatography , medicine , biochemistry , alternative medicine , organic chemistry , pathology , computer science , operating system
In this manuscript we present a new type of hydrogen optical metamaterial sensor based on the fabrication of Pd dendritic nanostructures. The fabrication of the sensor relies on a cheap self‐assembly process based on the pulsed electrodeposition method in nanoporous alumina templates. By performing optical transmission measurements, we demonstrate how this sensor can monitor hydrogen gas concentrations at room temperature either by evaluating the rate of signal decay during the Pd hydrogen absorption (transient regime) or by measuring the total variation in signal once the system achieves the equilibrium state (stationary regime). We take into account the effects of the Pd‐hydrogen phase transition and its size dependency to explain the kinetics of the hydrogen absorption and desorption in the studied samples. By using the transient detection method, the sensor is able to detect in approximately 50 s the explosive H 2 (g) concentration threshold of 4 % v/v at atmospheric pressure and room temperature.