Intermolecular Hydrogen Bonding in 2‐Fluoropyridine‐Water | Zendy

Gou  Qian | Zendy; Spada Lorenzo | Zendy; VallejoLopez  Montserrat | Zendy; Melandri Sonia | Zendy; Lesarri Alberto | Zendy; Cocinero Emilio J. | Zendy; Caminati Walther | Zendy

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Intermolecular Hydrogen Bonding in 2‐Fluoropyridine‐Water

Author(s) -

Gou Qian,

Spada Lorenzo,

VallejoLopez Montserrat,

Melandri Sonia,

Lesarri Alberto,

Cocinero Emilio J.,

Caminati Walther

Publication year - 2016

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201600370

Subject(s) - isotopologue , hydrogen bond , intermolecular force , molecule , proton , ring (chemistry) , chemistry , microwave , hydrogen , acceptor , rotational spectroscopy , crystallography , photochemistry , organic chemistry , physics , quantum mechanics , condensed matter physics

The hydration of 2‐fluoropyridine with one water molecule has been studied with a pulsed jet Fourier transform microwave technique. The rotational spectra of five isotopologues of the 1:1 complex have revealed the formation of a single most stable isomer. The observed cluster is characterized by an O−H⋅⋅⋅N hydrogen bond and a C−H⋅⋅⋅O weak hydrogen bond, where water is coplanar to the aromatic ring and acts in a double role of proton donor and proton acceptor.

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