Nickel‐Catalyzed Desulfitative C–C Cross Coupling: The Synthesis of 6‐Aza‐Tetrahydroquinazolines and their Solvatochromism | Zendy

Rajaguru Kandasamy | Zendy; Mariappan Arumugam | Zendy; Beneto Arockiam Jesin | Zendy; Sivaraman Gandhi | Zendy; Muthusubramanian Shanmugam | Zendy; Siva Ayyanar | Zendy; Bhuvanesh Nattamai | Zendy

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Nickel‐Catalyzed Desulfitative C–C Cross Coupling: The Synthesis of 6‐Aza‐Tetrahydroquinazolines and their Solvatochromism

Author(s) -

Rajaguru Kandasamy,

Mariappan Arumugam,

Beneto Arockiam Jesin,

Sivaraman Gandhi,

Muthusubramanian Shanmugam,

Siva Ayyanar,

Bhuvanesh Nattamai

Publication year - 2016

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201600361

Subject(s) - solvatochromism , nickel , catalysis , coupling (piping) , chemistry , combinatorial chemistry , pyrimidine , coupling reaction , stereochemistry , materials science , organic chemistry , molecule , metallurgy

A convenient nickel catalyzed approach towards the synthesis of diversely substituted 6‐aza‐tetrahydroquinazolines from pyrido‐pyrimidine‐2‐thione motifs with organo boronic acids by non‐basic desulfitative C−C cross coupling strategy is described. The absorption and emission spectral studies on some of the synthesised compounds reveal the existent of D‐π‐A−D systems displaying solvatochromism.

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