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Cardanol benzoxazine‐Sulfur Copolymers for Li‐S batteries: Symbiosis of Sustainability and Performance
Author(s) -
Shukla Swapnil,
Ghosh Arnab,
Sen Uttam Kumar,
Roy Prasun Kumar,
Mitra Sagar,
Lochab Bimlesh
Publication year - 2016
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201600050
Subject(s) - sulfur , cathode , copolymer , cardanol , materials science , electrolyte , faraday efficiency , chemical engineering , battery (electricity) , chemistry , composite material , metallurgy , power (physics) , physics , electrode , quantum mechanics , epoxy , engineering , polymer
A sulfur‐rich copolymer is synthesized via a sustainable, eco‐friendly approach using two major wastes namely, elemental sulfur (industrial waste) and cardanol (agro waste) and its application as cathode active material in Li−S battery. The presence of chemically bound sulfur (90 wt%) utilising cardanol (10 wt%) derivative in the copolymer (S90) showed a reduction in the active material dissolution into the electrolyte. In addition, the organic sulfur units get dispersed into the insoluble/insulating Li 2 S 2 /Li 2 S phase and thus found to suppress their irreversible deposition. Li−S battery based on S90/multi‐walled carbon nanotubes (MWCNT) (10 wt%) exhibited a reversible capacity of 1302 mAh g −1 at 2 nd cycle, maintaining a high reversible capacity of 928 mAh g −1 after 70 cycles at a relatively constant coulombic efficiency over 99 % at current rate of 200 mA g −1 . At 1000 mA g −1 current rate, the composite cathode delivered a reversible capacity of 697 mAh g −1 at 2 nd cycle and retained 75 % of its initial capacity even after 180 cycles.