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Factor analysis of Fe M 2,3 VV spectra of oxidizing iron: The role of the background in the emergence of ghost components
Author(s) -
Kooi Bart J.,
Somers Marcel A. J.
Publication year - 1994
Publication title -
surface and interface analysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.52
H-Index - 90
eISSN - 1096-9918
pISSN - 0142-2421
DOI - 10.1002/sia.740210802
Subject(s) - spectral line , principal component analysis , cascade , oxidizing agent , electron , chemistry , secondary electrons , analytical chemistry (journal) , physics , mathematics , statistics , nuclear physics , organic chemistry , chromatography , astronomy
The influence of the (correction for the) background in AES spectra on the results of factor analysis (FA) was investigated. To this purpose a set of experimental spectra for the Fe M 2,3 VV transition, obtained on the oxidation of pure iron, and sets of look‐alike simulated spectra, using a linear combination of two elastic components superimposed on background components, were analysed with FA after different types of treatment of the spectra prior to FA, e.g. differentiation or removal of a particular type of background. In the sets of simulated spectra the roles of a background due to the secondary electron cascade and that due to the inelastically scattered electrons were investigated separately. It was observed that for both types of backgrounds additional principal components with respect to the two elastic components arise, irrespective of the considered treatment of the spectra prior to FA. Results obtained for the experimental set and for the simulated sets with a background originating from the secondary electron cascade were very similar. In the simulated spectra, the origin of the additional components could be identified unambiguously as (an inadequate correction for) the background due to the secondary electron cascade. It is likely that the same origin applies to the additional (third) component emerging on FA of the set of experimental Fe M 2,3 VV spectra.