Premium
Adsorption of hydrogen fluoride on alumina
Author(s) -
Haverkamp R. G.,
Metson J. B.,
Hyland M. M.,
Welch B. J.
Publication year - 1992
Publication title -
surface and interface analysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.52
H-Index - 90
eISSN - 1096-9918
pISSN - 0142-2421
DOI - 10.1002/sia.740190127
Subject(s) - x ray photoelectron spectroscopy , adsorption , calcination , fluoride , chemistry , hydrogen fluoride , aluminium , hydrogen bond , inorganic chemistry , hydrogen , metal , absorption (acoustics) , catalysis , chemical engineering , materials science , molecule , organic chemistry , engineering , composite material
Abstract In the smelting of aluminium, HF fumes are produced that are subsequently trapped by absorption onto alumina. The factors that affect the adsorption capacity of alumina have been studied previously and are well established, but the mechanism by which HF adsorbs onto the alumina surface is not well understood. In this study, x‐ray photoelectron spectroscopy (XPS) was used to investigate the nature of the surface adsorption of HF on alumina. XPS is particularly well suited to the study of this type of gas adsorption process. Laboratory‐prepared samples were studied with particular interest in evidence for AlF bonding, or in fluoride species formed by reaction with OH or O. Also of interest was the role of sodium, since it is segregated to the surface of the alumina during calcination. AlF bonding was observed on only one sample type. An AlF interaction was identified when the alumina had been predried and dry HF was absorbed. When moisture was present no AlF 3 formation was observed. This suggests that under conventional conditions (i.e. moisture present) the adsorption of HF involves a weak interaction, probably hydrogen bonding, with intermediate layers of water. After heating the samples containing weakly bound HF to 500°C, no AlF interaction was observed. Much of the HF was desorbed at 700°C. An Na–F interaction was observed in all fluoride‐adsorbed samples; however, this can only account for a small proportion of the total fluoride adsorbed.