ESCA study of Cu/SiO 2  and Fe/SiO 2  interfaces heated in high vacuum | Zendy

Hirokawa Kichinosuke | Zendy; Yokokawa Yoshio | Zendy; Oku Masaoki | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

ESCA study of Cu/SiO 2 and Fe/SiO 2 interfaces heated in high vacuum

Author(s) -

Hirokawa Kichinosuke,

Yokokawa Yoshio,

Oku Masaoki

Publication year - 1981

Publication title -

surface and interface analysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.52

H-Index - 90

eISSN - 1096-9918

pISSN - 0142-2421

DOI - 10.1002/sia.740030205

Subject(s) - copper , oxide , ferrous , metal , oxidation state , oxygen , inorganic chemistry , chemistry , chemical state , iron oxide , analytical chemistry (journal) , materials science , metallurgy , x ray photoelectron spectroscopy , chemical engineering , organic chemistry , chromatography , engineering

The reaction at the interfacial region of Cu/SiO 2 and Fe/SiO 2 heated in the high vacuum of an ESCA spectrometer has been studied. Copper spread slightly into SiO 2 at 500–800°C in the metallic oxidation state. Cupric oxide formed on SiO 2 changed to cuprous oxide or cuprous oxide plus copper metal and slightly diffused into the SiO 2 by heating. Iron began to react with SiO 2 at about 600°C and migrated into SiO 2 in the ferrous oxidation state. This reaction was stimulated over 800°C and may be promoted by the presence of a small amount of oxygen on the iron surface.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research