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Succinonitrile as a high‐voltage additive in the electrolyte of LiNi 0.5 Co 0.2 Mn 0.3 O 2 /graphite full batteries
Author(s) -
Han Songyi,
Liu Yan,
Zhang Hong,
Fan Chaojun,
Fan Weizhen,
Yu Le,
Du Xueyong
Publication year - 2020
Publication title -
surface and interface analysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.52
H-Index - 90
eISSN - 1096-9918
pISSN - 0142-2421
DOI - 10.1002/sia.6744
Subject(s) - electrolyte , x ray photoelectron spectroscopy , electrochemistry , dielectric spectroscopy , lithium (medication) , graphite , linear sweep voltammetry , cyclic voltammetry , battery (electricity) , analytical chemistry (journal) , chemistry , succinonitrile , electrode , materials science , inorganic chemistry , chemical engineering , metallurgy , chromatography , medicine , power (physics) , physics , quantum mechanics , engineering , endocrinology
As a functional additive, succinonitrile (SN) can be used in LiNi 0.5 Co 0.2 Mn 0.3 O 2 /graphite lithium ion batteries to broaden the oxidation electrochemical window of the electrolyte and significantly improve its rate performance and high‐voltage cycle performance. Linear sweep voltammetry (LSV) shows that EC/EMC‐based electrolytes with SN have higher oxidation potentials (approximately 6.1 V vs Li/Li + ). The capacity retention of LiNi 0.5 Co 0.2 Mn 0.3 O 2 /graphite full cell with 0.5‐wt% SN added to the electrolyte and 120 cycles between 2.75 and 4.4 V was significantly increased from 67.96% to 84.0%. It is indicated that the LiNi 0.5 Co 0.2 Mn 0.3 O 2 (NCM523) battery containing 0.5‐wt% SN‐based electrolyte has better cycleability and capacity retention at high cutoff voltage. In addition, electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM), and X‐ray photoelectron spectroscopy (XPS) of the full cell were used to characterize the effect of SN on the cell. It is proved that the SN participates in the interfacial reaction between the electrode and the electrolyte to form a stable solid electrolyte interphase (SEI) layer, thereby effectively suppressing the increase of the charge transfer resistance and reducing the elution of the transition metal cations. These results indicate that SN can be used as a functional additive for high‐voltage lithium‐ion batteries.