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XPS study of structural transformations in some Ni complexes
Author(s) -
Naumkin A.,
Ivanova T.,
Sidorov A.,
Maslakov K.,
Kiskin M.,
Savilov S.,
Lunin V.,
Novotortsev V.,
Eremenko I.
Publication year - 2018
Publication title -
surface and interface analysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.52
H-Index - 90
eISSN - 1096-9918
pISSN - 0142-2421
DOI - 10.1002/sia.6427
Subject(s) - x ray photoelectron spectroscopy , chemistry , crystallography , nickel , nuclear magnetic resonance , physics , organic chemistry
X‐ray photoelectron spectroscopy investigations of Ni(L CH 3 ) 3 (Piv) 2 ( 1), [Ni(L CH 3 ) 2 ] 2 (Piv) 2 ) ( 2 ) , and [Ni(L CH 3 ) 2 ] 2 (CH 3 COO) 2 ] ( 3 ) complexes, where L CH3 —k 2 ‐1,2‐diamino‐4,5‐dimethylbenzene‐bis(k 1 ‐diamino‐4,5‐dimethylbenzene) and Piv—(CH 3 ) 3 CCOO, are reported and discussed. The photoelectron spectra are sensitive to the temperature of the samples and evidence on structural conformations.