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Adsorption of Zn(II) on graphene oxide prepared from low‐purity of amorphous graphite
Author(s) -
Yang Qiang,
Yang Guangcheng,
Peng Weijun,
Song Shaoxian
Publication year - 2017
Publication title -
surface and interface analysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.52
H-Index - 90
eISSN - 1096-9918
pISSN - 0142-2421
DOI - 10.1002/sia.6171
Subject(s) - adsorption , graphene , zeta potential , langmuir adsorption model , chemistry , oxide , amorphous solid , graphite , fourier transform infrared spectroscopy , aqueous solution , x ray photoelectron spectroscopy , inorganic chemistry , graphite oxide , chemical engineering , organic chemistry , nanoparticle , engineering
The adsorption of Zn(II) in aqueous solutions on graphene oxide (GO) prepared from low‐purity of natural amorphous graphite has been studied in this work. The study was performed through the measurements of Zeta potential, atomic force microscope, Fourier transform infrared spectrum and X‐ray photoelectron spectroscopy. The results indicated that the adsorption followed the Langmuir model with the maximum Zn(II) adsorption capacity of 73 mg/g at pH 7.0. In addition, the adsorption was well described by the pseudo‐second‐order kinetics model. The mechanism of the Zn(II) adsorption on GO was mainly attributed to chemical adsorption through complexation reaction between Zn(II) and hydroxyl or carboxyl groups on the GO sheets, while the electrostatic interaction also contribute to the whole interaction. Copyright © 2016 John Wiley & Sons, Ltd.