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Mass‐scale calibration of TOF‐SIMS spectra using quaternary ammonium ions
Author(s) -
Kobayashi Daisuke,
Otomo Shinya,
Aoyagi Satoka,
Itoh Hiroto
Publication year - 2014
Publication title -
surface and interface analysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.52
H-Index - 90
eISSN - 1096-9918
pISSN - 0142-2421
DOI - 10.1002/sia.5605
Subject(s) - chemistry , ion , mass spectrometry , mass spectrum , molecular mass , ammonium , analytical chemistry (journal) , chloride , secondary ion mass spectrometry , ammonium chloride , time of flight mass spectrometry , inorganic chemistry , chromatography , organic chemistry , enzyme , ionization
A novel method with quaternary ammonium salts as internal additives has been applied to the mass‐scale calibration of time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS). Five kinds of quaternary ammonium salts, octyltrimethylammonium bromide (C8TMA), tetradecyltrimethylammonium chloride (C14TMA), octadecyltrimethylammonium chloride (C18TMA), cetylpyridinium chloride (CPC) and benzyldimethyltetradecylammonium chloride (Bzl) were diluted with NH 3 aqueous solution and were mixed in equal quantities. The mixed solution was covered on a Si wafer and was measured by TOF‐SIMS. When molecular ions of C8TMA, C14TMA, and C18TMA were used for the mass‐scale calibration, the relative mass accuracy of low‐mass C X H Y fragment ions indicated negative values and depended on the carbon chain length and the degree of unsaturation. This result means that the conventional mass‐scale calibration with frequently employed low‐mass C X H Y fragment ions leads to degradation of the mass accuracy of high‐mass molecular ions. To improve the mass accuracy of molecular ions of CPC and Bzl, ions should be selected for the mass‐scale calibration in the following two ways: One way is for ions to consist only of molecular ions of C8TMA, C14TMA, and C18TMA, and the other way is for ions to include one of the molecular ions: C8TMA, C14TMA, and C18TMA, along with the C X H Y fragment ions. This novel mass‐scale calibration method is promising for realizing the correct identification of unknown high‐mass molecular ions. Those quaternary ammonium salts are powerful candidates of internal additives. Copyright © 2014 John Wiley & Sons, Ltd.