ToF‐SIMS study of 1‐dodecanethiol adsorption on Au, Ag, Cu and Pt surfaces | Zendy

Laiho Taina | Zendy; Leiro Jarkko A. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

ToF‐SIMS study of 1‐dodecanethiol adsorption on Au, Ag, Cu and Pt surfaces

Author(s) -

Laiho Taina,

Leiro Jarkko A.

Publication year - 2008

Publication title -

surface and interface analysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.52

H-Index - 90

eISSN - 1096-9918

pISSN - 0142-2421

DOI - 10.1002/sia.2722

Subject(s) - platinum , chemistry , secondary ion mass spectrometry , copper , adsorption , analytical chemistry (journal) , static secondary ion mass spectrometry , substrate (aquarium) , transition metal , metal , ion , mass spectrum , mass spectrometry , molecule , organic chemistry , catalysis , chromatography , oceanography , geology

Time‐of‐flight secondary ion mass spectrometry (ToF‐SIMS) has been used to perform a chemical analysis of long‐chain thiol (CH 3 (CH 2 ) 11 SH)‐treated gold, silver, copper and platinum surfaces. All the mass peaks from positive and negative ion spectra within the range m / z = 0–2000 u are studied. ToF‐SIMS data revealed that on gold, silver and copper substrates 1‐dodecanethiol form dense standing‐up phases, but on platinum being a catalytically active substrate, we were able to identify also surface‐aligned parallel lying molecules in addition to a standing thiolate layer. Our study shows that when ToF‐SIMS spectra are analyzed, not only the existence of oligomers but also metal + hydrocarbon fragments give information about the order of SAM. Copyright © 2008 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research