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XRD, AFM and IR investigations of ordered AlGaAs 2 phase in epitaxial Al x Ga 1– x As/GaAs (100) heterostructures
Author(s) -
Domashevskaya E. P.,
Seredin P. V.,
Lukin A. N.,
Bityutskaya L. A.,
Grechkina M. V.,
Arsentyev I. N.,
Vinokurov D. A.,
Tarasov I. S.
Publication year - 2006
Publication title -
surface and interface analysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.52
H-Index - 90
eISSN - 1096-9918
pISSN - 0142-2421
DOI - 10.1002/sia.2306
Subject(s) - epitaxy , heterojunction , lattice constant , metalorganic vapour phase epitaxy , materials science , superstructure , alloy , atomic force microscopy , lattice (music) , crystallography , analytical chemistry (journal) , chemistry , nanotechnology , diffraction , optoelectronics , optics , physics , metallurgy , layer (electronics) , chromatography , acoustics , thermodynamics
Abstract The lattice constant of Al x Ga 1− x As epitaxial alloys with various Al‐As( x ) content is determined for Al x Ga 1− x As/GaAs (100) heterostructures grown by MOVPE epitaxy using X‐ray diffractometry and X‐ray back‐reflections method. An ordered AlGaAs 2 (superstructural) phase was found in epitaxial heterostructures for x ∼ 0.50. The lattice constant of this phase along c axis is smaller than the double lattice constants of an Al 0.50 Ga 0.50 As alloy. Infrared (IR) reflection spectra of lattice vibrations were investigated in epitaxial heterostructures of Al x Ga 1− x As/GaAs (100) with different concentrations of Al in cation sublattice. In the sample with x ∼ 0.50, besides two main vibration modes some additional ones were found that correspond to superstructure ordered phase AlGaAs 2 . Atomic‐force microscopy (AFM) of the sample surface with x ∼ 0.50 demonstrated the presence of areas with ordered nano‐relief having period of ∼115 nm that can be related with superstructure phase of AlGaAs 2 . Copyright © 2006 John Wiley & Sons, Ltd.