Adsorption behaviour of C 2 H 5 SCH 3  on Ag(111) and Ag(UFP) surfaces | Zendy

Sardar S. A. | Zendy; Syed J. A. | Zendy; Yagi S. | Zendy; Tanaka K. | Zendy

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Adsorption behaviour of C 2 H 5 SCH 3 on Ag(111) and Ag(UFP) surfaces

Author(s) -

Sardar S. A.,

Syed J. A.,

Yagi S.,

Tanaka K.

Publication year - 2003

Publication title -

surface and interface analysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.52

H-Index - 90

eISSN - 1096-9918

pISSN - 0142-2421

DOI - 10.1002/sia.1628

Subject(s) - adsorption , x ray photoelectron spectroscopy , molecule , chemistry , spectroscopy , crystallography , analytical chemistry (journal) , physics , nuclear magnetic resonance , organic chemistry , quantum mechanics

The adsorption behaviour of ethylmethylsulfide (C 2 H 5 SCH 3 ) on Ag(111) and ultrafine particle Ag, Ag(UFP), surfaces has been studied by near‐edge x‐ray absorption fine structure and x‐ray photoelectron spectroscopy techniques. It is found that C 2 H 5 SCH 3 adsorbs molecularly on the Ag(111) surface but dissociates on Ag(UFP). On the Ag(111) surface the molecule shows polarization dependence. The S–C 2 H 5 and S–CH 3 bonds are found to be tilted at angles of 31 ± 5° and 21 ± 5° from the surface, respectively. Copyright © 2003 John Wiley & Sons, Ltd.

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