Open AccessOxidative methylation of (η 5 ‐C 5 Me 5 ) 2 TiX (X = Cl, OMe, Me) with group 12 dimethyl complexes to diamagnetic (η 5 ‐C 5 Me 5 ) 2 TiX(Me)
Author(s) -
Luinstra Gerrit A.,
Teuben Jan H.
Publication year - 1991
Publication title -
recueil des travaux chimiques des pays‐bas
Language(s) - English
Resource type - Journals
ISSN - 0165-0513
DOI - 10.1002/recl.19911100206
Subject(s) - diamagnetism , chemistry , alkylation , group (periodic table) , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry , catalysis , physics , quantum mechanics , magnetic field
Tervalent titanium compounds (C 5 Me 5 ) 2 TiX (X = OMe, Cl, Me) are selectively oxidized and alkylated at room temperature by ZnMe 2 to diamagnetic monomethyl derivatives (C 5 Me 5 ) 2 TiX(Me).
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