Characterization of silsesquioxanes by size‐exclusion chromatography and matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometry | Zendy

Falkenhagen Jana | Zendy; Jancke Harald | Zendy; Krüger RalphPeter | Zendy; Rikowski Eckhard | Zendy; Schulz Günter | Zendy

Premium

Characterization of silsesquioxanes by size‐exclusion chromatography and matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometry

Author(s) -

Falkenhagen Jana,

Jancke Harald,

Krüger RalphPeter,

Rikowski Eckhard,

Schulz Günter

Publication year - 2003

Publication title -

rapid communications in mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.528

H-Index - 136

eISSN - 1097-0231

pISSN - 0951-4198

DOI - 10.1002/rcm.911

Subject(s) - chemistry , silsesquioxane , mass spectrometry , desorption , ionization , matrix assisted laser desorption/ionization , size exclusion chromatography , characterization (materials science) , analytical chemistry (journal) , chromatography , time of flight mass spectrometry , ion , organic chemistry , polymer , adsorption , nanotechnology , enzyme , materials science

Liquid chromatography in combination with spectroscopic methods like matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometry (MALDI‐TOFMS) or nuclear magnetic resonance (NMR) spectroscopy is a powerful method to characterize silsesquioxanes and silsesquioxane mixtures. As new examples, the formation of silsesquioxyl‐substituted silsesquioxanes [(n‐octyl) 7 (SiO 1.5 ) 8 ] 2 O and [(n‐octyl) 7 (SiO 1.5 ) 8 O] 2 [(n‐octyl) 6 (SiO 1.5 ) 8 ] as well as the cage rearrangement of octa‐[(n‐heptyl)silsesquioxane] to larger structur es [(n‐heptyl)SiO 1.5 )] n up to n=28 are shown. Copyright © 2003 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research