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Three certified sugar reference materials for carbon isotope delta measurements
Author(s) -
Chartrand Michelle M.G.,
Meija Juris,
Kumkrong Paramee,
Mester Zoltan
Publication year - 2019
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.8357
Subject(s) - chemistry , certified reference materials , sugar beet , isotope analysis , stable isotope ratio , isotope , analytical chemistry (journal) , environmental chemistry , chromatography , detection limit , geology , archaeology , nuclear physics , oceanography , physics , history
Rationale For isotope delta analysis, it is preferable to have at least two matrix‐matched reference materials whose isotope delta values encompass those of the samples to be analyzed. The National Research Council Canada (NRC) has developed three sugar Certified Reference Materials (CRMs), BEET‐1 (beet sugar), GALT‐1 (galactose), and FRUT‐1 (fructose), to be collectively used for carbon isotope delta measurements in sugars, and other organic materials. Methods All materials were homogenized and packaged in glass ampules. All three sugar materials were analyzed at the NRC using elemental analyzer/isotope ratio mass spectrometry (EA/IRMS). Six additional laboratories also provided EA/IRMS measurements. Data from all laboratories were re‐normalized using three international secondary reference materials (IAEA‐CH‐6, USGS40, and USGS62) included as blind samples in the inter‐laboratory comparison, thus providing added quality control and robustness to the study. Results Re‐normalized carbon isotope delta values from each laboratory were combined using a random laboratory effects statistical model with accounting of the correlations between the laboratory results due to the use of the same reference materials for calibration. The consensus δ( 13 C) values and combined standard uncertainties which include effects due to characterization, homogeneity, and stability for BEET‐1, GALT‐1, and FRUT‐1 are −26.02(7) ‰, −21.41(6) ‰, and −10.98(5) ‰, respectively, on the VPDB scale. Conclusions Three new δ( 13 C) sugar CRMs (BEET‐1, GALT‐1, and FRUT‐1) were developed and are available from NRC. These three CRMs can be utilized as a set for daily δ( 13 C) scale normalization of sugar‐based or other organic materials in order to produce reliable δ( 13 C) measurements.