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Detection of 135 Cs by accelerator mass spectrometry
Author(s) -
MacDonald C.,
Charles C. R. J.,
Cornett R. J.,
Zhao X. L.,
Kieser W. E.,
Litherland A. E.
Publication year - 2014
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.7083
Subject(s) - chemistry , accelerator mass spectrometry , isobar , isotope , isobaric process , mass spectrometry , analytical chemistry (journal) , radiochemistry , natural abundance , ion , stable isotope ratio , separator (oil production) , nuclear physics , chromatography , physics , nucleon , organic chemistry , thermodynamics
RATIONALE The ability to measure both 135 Cs and 137 Cs can provide an estimate of the age and source of Cs isotopes in an environmental sample. Accelerator mass spectrometry (AMS) consistently reports lower abundance sensitivities than other techniques and, with the addition of an on‐line reaction cell, simpler isobaric suppression. Therefore, an AMS methodology was developed to measure Cs isotopes using Cs F 2 − as the initial anion. METHODS The ion beam is passed through the Isobar Separator for Anions (ISA) where it is captured by radiofrequency quadrupoles in a gas cell before injection into the tandem accelerator. In the ISA, the beam reacts with O 2 gas, selectively removing the Ba F 2 − and leaving the Cs analyte to be reaccelerated and sent through the remainder of the AMS system. RESULTS The Ba F 2 − signal was attenuated by a factor of 10 5 in the ISA while 25% of the original Cs F 2 − current was transmitted into the accelerator. 135 Cs was measured without any interference from 133 Cs to an abundance sensitivity of 1.3 × 10 –10 . The abundances of four stable Ba isotopes (masses 133, 134, 135 and 137) were measured and no isotope‐dependent bias was detected using the ISA in vacuum. CONCLUSIONS The results demonstrate the feasibility of measuring long‐lived Cs isotopes without Ba interference by AMS with on‐line isobar separation and the ability to use shorter lived Cs isotopes for yield tracing. Copyright © 2014 John Wiley & Sons, Ltd.