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Determination of trace quaternary ammonium surfactants in water by combining solid‐phase extraction with surface‐assisted laser desorption/ionization mass spectrometry
Author(s) -
Chen YuChie,
Sun MeiChuan
Publication year - 2001
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.534
Subject(s) - chemistry , solid phase extraction , sorbent , detection limit , desorption , extraction (chemistry) , alkyl , mass spectrometry , chromatography , elution , ammonium bromide , bromide , ammonium , aqueous solution , analytical chemistry (journal) , adsorption , inorganic chemistry , pulmonary surfactant , organic chemistry , biochemistry
This study demonstrates the feasibility of combining solid‐phase extraction (SPE) with surface‐assisted laser desorption/ionization (SALDI) mass spectrometry to determine trace quaternary ammonium surfactants in water. The trace surfactants in water were directly concentrated on the surface of activated carbon sorbent in SPE. The activated carbon sorbent was then mixed with the SALDI liquid for SALDI analysis. No SPE elution procedure was necessary. Experimental results indicate that the surfactants with longer chain alkyl groups exhibit higher sensitivities than those with shorter chain alkyl groups in SPE‐SALDI analysis. The detection limit for hexadecyltrimethylammonium bromide is around 10 ppt in SPE‐SALDI analysis by sampling 100 mL of aqueous solution, while that of tetradecyltrimethylammonium bromide is about 100 ppt. The detection limit for decyltrimethylammonium bromide and dodecyltrimethylammonium bromide is in the low‐ppb range. Copyright © 2001 John Wiley & Sons, Ltd.