Production and isolation of ligated metal(IV)‐oxo ions by tandem mass spectrometry | Zendy

Taylor Ivan F. | Zendy; Blanksby Stephen J. | Zendy; Colbran Stephen B. | Zendy; Willett Gary D. | Zendy

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Production and isolation of ligated metal(IV)‐oxo ions by tandem mass spectrometry

Author(s) -

Taylor Ivan F.,

Blanksby Stephen J.,

Colbran Stephen B.,

Willett Gary D.

Publication year - 2010

Publication title -

rapid communications in mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.528

H-Index - 136

eISSN - 1097-0231

pISSN - 0951-4198

DOI - 10.1002/rcm.4493

Subject(s) - chemistry , tandem mass spectrometry , isolation (microbiology) , tandem , mass spectrometry , metal ions in aqueous solution , chromatography , metal , organic chemistry , microbiology and biotechnology , biology , materials science , composite material

High valent metal(IV)‐oxo species, [M(O)(MeIm) n (OAc)] + (M = Mn–Ni, MeIm = 1‐methylimidazole, n = 1–2), which are relevant to biology and oxidative catalysis, were produced and isolated in gas‐phase reactions of the metal(II) precursor ions [M(MeIm) n (OAc)] + (M = Mn–Zn, n = 1–3) with ozone. The precursor ions [M(MeIm)(OAc)] + and [M(MeIm) 2 (OAc)] + were generated via collision‐induced dissociation of the corresponding [M(MeIm) 3 (OAc)] + ion. The dependence of ozone reactivity on metal and coordination number is discussed. Copyright © 2010 John Wiley & Sons, Ltd.

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