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Hydrogen isotope analysis of natural abundance and deuterium‐enriched waters by reduction over chromium on‐line to a dynamic dual inlet isotope‐ratio mass spectrometer
Author(s) -
Donnelly Terry,
Waldron Susan,
Tait Andrew,
Dougans Julie,
Bearhop Stuart
Publication year - 2001
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.361
Subject(s) - chemistry , deuterium , isotope , mass spectrometry , inlet , chromium , analytical chemistry (journal) , seawater , isotope analysis , stable isotope ratio , abundance (ecology) , environmental chemistry , oceanography , nuclear physics , chromatography , ecology , geology , physics , organic chemistry , biology
This paper describes the application of a simple chromium reduction furnace which can be interfaced with a dual inlet isotope‐ratio mass spectrometer thus providing the capacity for cheap, fast, accurate and precise measurement of δD V−SMOW by dynamic mass spectrometry. Measurements are precise to the order of ≤0.5‰. Mean 95% confidence intervals for the Vienna Standard Mean Ocean Water (V‐SMOW) to Standard Light Antarctic Precipitation (SLAP) range are in the order of 2.5‰ and the system is linear over the range −428 to 23,000‰. Memory effects do exist, but are small for natural abundance samples and can be minimised by careful planning of the analytical load. Copyright © 2001 John Wiley & Sons, Ltd.