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A systematic study of carboxylic acids in negative ion mode electrospray ionisation mass spectrometry providing a structural model for ion suppression
Author(s) -
Clifford Mike N.,
Lopez Violeta,
Poquet Laure,
Williamson Gary,
Kuhnert Nikolai
Publication year - 2007
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.3038
Subject(s) - chemistry , electrospray , mass spectrometry , ion , electrospray ionization , chromatography , analytical chemistry (journal) , organic chemistry
We report a systematic investigation of the effects and structural requirements for ion suppression in negative ion mode electrospray ionisation mass spectrometry of a series of carboxylic acids and present a structural model rationalising ion suppression effects. Copyright © 2007 John Wiley & Sons, Ltd.
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