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Gas chromatography/mass spectrometric analysis of N , N ‐dialkylaminoethyl‐2‐chlorides and trimethylsilyl derivatives of N , N ‐dialkylaminoethan‐2‐ols for verification of the Chemical Weapons Convention
Author(s) -
Gupta Arvinda K.,
Pardasani Deepak,
Kanaujia Pankaj K.,
Tak Vijay,
Dubey Devendra K.
Publication year - 2006
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.2569
Subject(s) - chemistry , trimethylsilyl , electron ionization , mass spectrum , fragmentation (computing) , gas chromatography , mass spectrometry , chromatography , ion , chemical ionization , gas chromatography–mass spectrometry , analytical chemistry (journal) , medicinal chemistry , ionization , organic chemistry , computer science , operating system
Gas chromatography/electron ionization mass spectrometry (GC/EI‐MS) of N , N ‐dialkylaminoethyl‐2‐chlorides (DAAECls) and trimethylsilyl (TMS) derivatives of N , N ‐dialkylaminoethan‐2‐ols (DAAEAs) has been carried out. GC/EI‐MS data of these compounds are of importance for verification of the Chemical Weapons Convention (CWC). Based on these EI mass spectra, generalized fragmentation routes are proposed that rationalize most of the characteristic ions. Copyright © 2006 John Wiley & Sons, Ltd.