Premium
New experiments on HNCSe and HCNSe radical cations
Author(s) -
Gerbaux P.,
Dechamps N.,
Flammang R.,
Nagi Reddy P.,
Srinivas R.
Publication year - 2005
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.2276
Subject(s) - chemistry , mass spectrometry , ion , dimethyl sulfide , ionization , molecule , sulfide , radical ion , nitric acid , inorganic chemistry , photochemistry , sulfur , organic chemistry , chromatography
Dissociative ionization of the selenourea SeC(NH 2 ) 2 (2) conveniently generates beams of pure isocyanoselenic acid radical cations. The HNCSe . + connectivity is established by collisional activation and by associative ion‐molecule reactions with dimethyl sulfide or nitric oxide using a large‐scale hybrid mass spectrometer. Copyright © 2005 John Wiley & Sons, Ltd.