Dynamic headspace: a single‐step extraction for isotopic analysis of μg/L concentrations of dissolved chlorinated ethenes

In this study a dynamic headspace method was developed to measure the carbon isotope values of dissolved chlorinated ethenes at μg/L concentrations. A gas chromatograph/combustion/isotope ratio mass spectrometer (GC/C/IRMS) was modified to include a headspace extraction system followed by a cryogenic trap. Extracting headspace from a 160 mL vial with 80 mL of aqueous solution and 40 g of NaCl for 8–12 min resulted in accurate and reproducible δ 13 C values for trichloroethene (TCE) and cis‐1,2‐dichloroethene (cDCE) at concentrations of 50–75 μg/L. Based on these results a conservative lower limit of quantitation of 38 μg/L can be calculated for these compounds. For more volatile compounds such as tetrachloroethene (PCE) and vinyl chloride (VC), field data analyzed using this method indicate a lower limit of quantitation in the tens of μg /L range. Copyright © 2004 John Wiley & Sons, Ltd.